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2.2]decane Main and defining the geometry from the exocyclic double bond. The activation energies of development from the vinyl-gold intermediates had been calculated and disclosed a silyl enol ether having an unprotected indole moiety as a suitable precursor with the Toste cyclization. This 6-step synthesis did not require any nonstrategic redox m
2.two]decane Main and defining the geometry with the exocyclic double bond. The activation energies of formation of the vinyl-gold intermediates ended up calculated and uncovered a silyl enol ether with the unprotected indole moiety as an acceptable precursor for the Toste cyclization. This 6-step synthesis didn't contain any nonstrategic redox man